As the phosphorite contains both carbonate and silicate minerals, neither single direct floatation nor single reverse floatation can obtain a good floatation index.
由于该磷矿既含碳酸盐矿物,也含硅酸矿物,因此单一正浮选或者单一的反浮选较难获得较好的选矿指标。
From the above researches it is found that neither direct floatation nor single reverse floatation can achieve a concentrate grade of more than 30%. As the content of carbonate in the rock is fairly high, the combination of floatation and roasting digestion is investigated. Concentrate of direct floatation is roasted under different high temperatures for two to three hours and then cooled down. Then some water is added in to mix with and assimilate the concentrate. After that the concentrate is filtered and its grade analyzed.
In single reverse floatation the concentrate grade is 23.88% at most. Therefore single reverse floatation is not desirable for concentration of calcareous rock.
采用单一反浮选该精矿的品位最高也只有23.88%,因此单一反浮选不适用钙磷矿的选矿。
As the rock has a fairly high content of carbonate, a single reverse floatation test is conducted.
由于该矿含碳酸盐矿物的量较高,因此,采用单一反浮选进行了试验。
Other results
Direct and reverse floatation is a proper process of floatation for the rock. However in reverse floatation only H3PO4 may be added as a regulator and inhibitor, not H2SO4.
正反浮选是该矿石适宜的选矿工艺,在反浮选只能添加磷酸作为调整剂和抑制剂,不能添加硫酸。
For calcareous phosphate rock, the technology of normal temperature direct-reverse flotation was applied, and meanwhile, the effect of single reverse flotation, direct flotation roasting and heating flotation for flotation was explored, and in normal temperature direct-reverse flotation, the effect of grinding fineness and various chemicals for ore dressing indexes was researched.
Based on the above test the grinding finenesses and dosages of direct floatation reagents including sodium carbonate, sodium silicate, and TSK-125 are determined and a test of H3PO4 dosage in reverse floatation is carried out.
As in the above researches it is quite hard to raise concentrate grade, heating is applied to carry out heated the heated floatation, effect of the carbonate mineral inhibitor NO-2 upon floatation is studied; a test of reverse floatation is done with addition of H2SO4 or H3PO4 to floated concentrate.
In reverse floatation, when H3PO4 dosage is the same, the ore dressing efficiency is the highest when H2SO4 dosage is 15.0 kg/t. When H3PO4 dosage is small, concentrate grade is relatively low. In the above test, no grade reaches above 30%.
In accordance with nature of ores, different technologies may be applied. For silica phosphatic rock, the technology of single direct flotation or dense selection may be applied to improve concentrate grade and eliminate its silica gangue; for calcareous and magnesite phosphatic rock, single reverse flotation shall be chosen to remove calcareous and magnesite gangue; for complex phosphate mine, namely the mine containing both silicate gangue and carbonate gangue with different transitional types, the technology of direct-reverse flotation shall be chosen with different flotation technology emphasized; for transitional phosphate rock with high content of silicate, the focus is direct flotation technology, otherwise the focus is reverse flotation technology to remove carbonate or use double reverse flotation technology to eliminate impurity.
In heated direct and reverse floatation, concentrate grade still fails to reach 30%. The ore dressing efficiency does not increase much in direct floatation with addition of a carbonate inhibitor NO-2. Hence in subsequent tests no heating is provided nor NO-2. But from the test result we find that addition of H3PO4 in reverse floatation may increase concentrate grades.
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